Linnaeite

Formula : Co3S4

Family: 
Sulfides
Space group: 
Isometric - Hexoctahedral HM symbol (4/m -3 2/m) Space Group: F d3m
Dana class: 
2.10.1.1II- 2 Sulfide Minerals ; 2.10 Sulfides - Including Selenides and Tellurides where Am Bn Xp, with (m+n):p=3:4 ; 2.10.1 Linnaeite Group (Isometric: Fd3m)

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
305.064 62.550 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. -361878 (Ref.: Internal calculation) -374500 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. 176.000 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. 162.66 (Ref.: 87pan/mah) Pankratz L. B., 1987, A. D. Mah, and S. W. Watson, Thermodynamic Properties of Sulfides (U. S. Bureau of Mines Bulletin 689, 1987, 427 p).
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
150.55 86.77 -12.23 (Ref.: 87pan/mah) Pankratz L. B., 1987, A. D. Mah, and S. W. Watson, Thermodynamic Properties of Sulfides (U. S. Bureau of Mines Bulletin 689, 1987, 427 p).
Reaction properties

Linnaeite + 2H+ + 0.75H2O ⇌ 3Co+2 + 3.5HS- + 0.25S2O3-2

298.15 K, 1 bar log10K: -49.97 ΔH°r:195951 J·mol-1 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp.
T(°C) 0 25 60 100 150 200 250 300
log10K -53.27 -49.97 -46.56 -43.82 -41.66 -40.59 -40.50 -41.57
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-3522.676288 -0.568295 181014.783933 1278.182494 -11357129.133073