HVO₄^-²

Formula : HVO₄^-²

Dernière mise à jour le 25.01.2021

Individual properties (298.15 K)

M g·mol^-1	V° cm³·mol^-1	ΔGº_f J·mol^-1	ΔHº_f J·mol^-1	Sº J·mol^-1·k^-1	C_P J·mol^-1·K^-1
115.947	12.263 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.	-974872 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.	-1159285 (Ref.: Internal calculation)	16.736 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.	378.20 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.

HKF coefficients

a₁·10 J·mol^-1·bar^-1	a₂·10^-2 J·mol^-1	a₃ J·K·mol^-1·bar^-1	a₄·10^-4 J·K·mol^-1	c₁ J·mol^-1·K^-1	c₂·10^-4 J·K·mol^-1	ω·10^-5 J·mol^-1
18.9995	13.8394	18.6058	-12.1989	361.3950	61.7073	13.1909

Reaction properties

VO₂⁺ + 2H₂O ⇌ HVO₄^-² + 3H⁺

298.15 K, 1 bar log₁₀K: -15.14 ΔH°_r:62301 J·mol^-1

T(°C)	0	25	60	100	150	200	250	300
log₁₀K	-16.07	-15.14	-13.92	-12.71	-11.46	-10.48	-9.79	-9.47

log₁₀K(T) = A + B·T + C·T^-1 + D·log₁₀(T) + E·T⁻² (T in Kelvin)

A	B	C	D	E
-627.652737	-0.111260	23415.515811	233.461970	-936959.344879