Carbonate(K)

Formula : K2CO3:1.5H2O

Family: 
Carbonates

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
165.228 -1431333 (Ref.: 84har/mol) Harvie C.E., Moller N., and Weare J.H.. 1984, The prediction of mineral solubilities in natural waters: The Na-K-Mg-Ca-H-Cl-SO4-OH-HCO3-CO3-CO2-H2O system to high ionic strengths at 25 C. Geochimica Cosmochimica Acta, 48, pp. 723-751. -1607066 (Ref.: Internal calculation) 203.300 (Ref.: 82wag/eva) Wagman D.D., Evans W.H., Parker V.B., Schumm R.H., Halow I., Bailey S.M., Churney K.L., and Nutall R.L., 1982. The NBS Tables of Chemical Thermodynamic Properties. J. Phys. Chem. Ref. Data, 11, Suppl. 2.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
Reaction properties

Carbonate(K) + H+ ⇌ HCO3- + 2K+ + 1.5H2O

298.15 K, 1 bar log10K: 13.36 ΔH°r:-15889 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K 13.63 13.36 13.10 12.94 12.86 12.83 12.79 12.62
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-843.108542 -0.121938 46997.674769 308.651716 -2537614.678512