Phillipsite(Ca)

Formula : Ca0.5AlSi3O8:3H2O

Family: 
Zeolites
Space group: 
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: P 21/m
Dana class: 
77.1.3.6a (77) Tectosilicate Zeolite group (77.1) true zeolites (77.1.3) Gismondine and related species
High temperature: 
See Laumontite
Geological context: 
low temperature alteraton of plagioclase in volcanic rocks

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
313.318 151.150 (Ref.: 97coo/alb) Coombs, D.S., Alberti, A., Armbruster, T., Artioli, G., Colella, C., Galli, E., Grice, J.D., Liebau, F., Mandarino, J.A., Minato, H., Nickel, E.H., Passaglia, E., Peacor, D.R., Quartieri, S., Rinaldi, R., Ross, M., Sheppard, R.A., Tillmanns, E., Vealini, G., 1997. Recommended nomenclature for zeolite minerals - report of the subcommittee on zeolites of the international mineralogical association, commission on new minerals and mineral names. Canadian Mineralogist, 35, 1571-1606. -4441431 (Ref.: 09bla) Blanc P. (2009) - Thermochimie - Selection de constantes thermodynamiques pour les zeolites : version 2. Rapport final. Rapport BRGM/RP-57796-FR. 55 p. -4824113 (Ref.: Internal calculation) 342.380 (Ref.: 09bla) Blanc P. (2009) - Thermochimie - Selection de constantes thermodynamiques pour les zeolites : version 2. Rapport final. Rapport BRGM/RP-57796-FR. 55 p. 333.00 (Ref.: 10vie) Vieillard P., 2010 - A predictive model for the entropies and heat capacities of zeolites. Eur. J. Mineral. 22, 823-836
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
333.00 0.00 0.00 (Ref.: 10vie) Vieillard P., 2010 - A predictive model for the entropies and heat capacities of zeolites. Eur. J. Mineral. 22, 823-836
Reaction properties

Phillipsite(Ca) + 4H+ + H2O ⇌ Al+3 + 0.5Ca+2 + 3H4SiO4

298.15 K, 1 bar log10K: 2.32 ΔH°r:-76540 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K 3.43 2.32 0.84 -0.55 -1.92 -3.01 -3.96 -4.90
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-1654.719108 -0.214959 103532.889146 584.394793 -6415402.059939