Anthophyllite

Formula : Mg7Si8O22(OH)2

Family: 
Amphiboles
Space group: 
Orthorhombic - Dipyramidal H-M Symbol (2/m 2/m 2/m) Space Group: P nma
Dana class: 
66.1.2.2 (66) Inosilicate Double-Width Unbranched Chains, W=2 (66.1) Dana Type (66.1.2) Group 1, the Mg-Fe-Mn-Li amphiboles (Orthorhombic)
High temperature: 
Anthophyllite is stable from 200C to about 700C.
Geological context: 
Occurs from medium- or high-grade metamorphism, in amphibolites, gneisses, metaquartzites, iron formations, granulites, and schists derived from argillaceous sediments, ultramafic, or mafic igneous rocks; also a retrograde reaction product.

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
780.820 265.400 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. -11343357 (Ref.: Internal calculation) -12070000 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. 534.500 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. 663.01 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
815.11 248.20 -200.99 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp.
Reaction properties

Anthophyllite + 14H+ + 8H2O ⇌ 7Mg+2 + 8H4SiO4

298.15 K, 1 bar log10K: 73.78 ΔH°r:-583247 J·mol-1 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp.
T(°C) 0 25 60 100 150 200 250 300
log10K 82.84 73.78 62.89 52.87 43.05 35.23 28.64 22.62
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-5232.162211 -0.700799 338455.923268 1857.998406 -19360477.178099