As2O5

Formula : As2O5

Family: 
Oxides

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
229.840 53.204 (Ref.: 84pan/stu) L.B. Pankratz, J.M. Stuve, and N.A. Gokcen, 'Thermodynamic Data for Mineral Technology,' Bulletin 677, U.S. Bureau of Mines (1984). -782110 (Ref.: Internal calculation) -924870 (Ref.: 01gas/aza) Gaskova O., Azaroual M., Piantone, P., Lassin A. (2001) - Arsenic behaviour in subsurface hydrogeochemical systems - A critical review of thermodynamic data forarsenic minerals and aqueous species - A compilation of arsenic surface complexation reactions. BRGM Report RP-51356-FR, 78 p. 105.440 (Ref.: 01gas/aza) Gaskova O., Azaroual M., Piantone, P., Lassin A. (2001) - Arsenic behaviour in subsurface hydrogeochemical systems - A critical review of thermodynamic data forarsenic minerals and aqueous species - A compilation of arsenic surface complexation reactions. BRGM Report RP-51356-FR, 78 p. 115.90 (Ref.: 01gas/aza) Gaskova O., Azaroual M., Piantone, P., Lassin A. (2001) - Arsenic behaviour in subsurface hydrogeochemical systems - A critical review of thermodynamic data forarsenic minerals and aqueous species - A compilation of arsenic surface complexation reactions. BRGM Report RP-51356-FR, 78 p.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
115.90 0.00 0.00 (Ref.: 01gas/aza) Gaskova O., Azaroual M., Piantone, P., Lassin A. (2001) - Arsenic behaviour in subsurface hydrogeochemical systems - A critical review of thermodynamic data forarsenic minerals and aqueous species - A compilation of arsenic surface complexation reactions. BRGM Report RP-51356-FR, 78 p.
Reaction properties

As2O5 + 3H2O ⇌ 2H2AsO4- + 2H+

298.15 K, 1 bar log10K: 2.24 ΔH°r:-36939 J·mol-1 (Ref.: 01gas/aza) Gaskova O., Azaroual M., Piantone, P., Lassin A. (2001) - Arsenic behaviour in subsurface hydrogeochemical systems - A critical review of thermodynamic data forarsenic minerals and aqueous species - A compilation of arsenic surface complexation reactions. BRGM Report RP-51356-FR, 78 p.
T(°C) 0 25 60 100 150 200 250 300
log10K 2.76 2.24 1.46 0.53 -0.65 -1.87 -3.17 -4.67
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-1042.542139 -0.176484 58968.028884 379.523893 -3510210.909266