Burkeite

Formula : Na6CO3(SO4)2

Space group: 
Orthorhombic - Dipyramidal HM symbol (2/m 2/m 2/m) Space Group: P mmm
Dana class: 
32.1.1.1VI- 32 Compound Sulfates ; 32.1 Compound Sulfates (anhydrous) with simple bi-anionic formula ; 31.10.6

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
390.075 151.200 (Ref.: 63wyc) Wyckoff, R.W.G., 1963, Crystal Structures, Second edition, tome 4, Interscience Publishers, New York, p. 320-322. -3650967 (Ref.: 84har/mol) Harvie C.E., Moller N., and Weare J.H.. 1984, The prediction of mineral solubilities in natural waters: The Na-K-Mg-Ca-H-Cl-SO4-OH-HCO3-CO3-CO2-H2O system to high ionic strengths at 25 C. Geochimica Cosmochimica Acta, 48, pp. 723-751.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
Reaction properties

Burkeite + H+ ⇌ HCO3- + 6Na+ + 2SO4-2

298.15 K, 1 bar log10K: -0.77 ΔH°r: J·mol-1 (Ref.: )
T(°C) 0 25 60 100 150 200 250 300
log10K -0.77 -0.77 -0.77 -0.77 -0.77 -0.77 -0.77 -0.77
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-0.770000 0.000000 0.000000 0.000000 0.000000