C0.7A0.01SH

Formula : Ca1.4Al0.04Si2O6.0128H1.1056:1.4156H2O

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
236.177 105.110 (Ref.: 18roo/vie) Roosz, C., Vieillard, P., Blanc, P., Gaboreau, S., Gailhanou, H., Braithwaite, D., Montouillout, V., Denoyel, R., Henocq, P., Made, B., 2018. Thermodynamic properties of C-S-H, C-A-S-H and M-S-H phases: Results from direct measurements and predictive modelling. Applied Geochemistry 92, 140-156. -3173942 (Ref.: 18roo/vie) Roosz, C., Vieillard, P., Blanc, P., Gaboreau, S., Gailhanou, H., Braithwaite, D., Montouillout, V., Denoyel, R., Henocq, P., Made, B., 2018. Thermodynamic properties of C-S-H, C-A-S-H and M-S-H phases: Results from direct measurements and predictive modelling. Applied Geochemistry 92, 140-156. -3432156 (Ref.: Internal calculation) 250.132 (Ref.: 18roo/vie) Roosz, C., Vieillard, P., Blanc, P., Gaboreau, S., Gailhanou, H., Braithwaite, D., Montouillout, V., Denoyel, R., Henocq, P., Made, B., 2018. Thermodynamic properties of C-S-H, C-A-S-H and M-S-H phases: Results from direct measurements and predictive modelling. Applied Geochemistry 92, 140-156. 253.55 (Ref.: 18roo/vie) Roosz, C., Vieillard, P., Blanc, P., Gaboreau, S., Gailhanou, H., Braithwaite, D., Montouillout, V., Denoyel, R., Henocq, P., Made, B., 2018. Thermodynamic properties of C-S-H, C-A-S-H and M-S-H phases: Results from direct measurements and predictive modelling. Applied Geochemistry 92, 140-156.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
253.55 0.00 0.00 (Ref.: 18roo/vie) Roosz, C., Vieillard, P., Blanc, P., Gaboreau, S., Gailhanou, H., Braithwaite, D., Montouillout, V., Denoyel, R., Henocq, P., Made, B., 2018. Thermodynamic properties of C-S-H, C-A-S-H and M-S-H phases: Results from direct measurements and predictive modelling. Applied Geochemistry 92, 140-156.
Reaction properties

C0.7A0.01SH + 2.92H+ + 0.5716H2O ⇌ 0.04Al+3 + 1.4Ca+2 + 2H4SiO4

298.15 K, 1 bar log10K: 17.95 ΔH°r:-103921 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K 19.55 17.95 16.00 14.20 12.44 11.07 9.94 8.91
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-1096.564740 -0.141910 71801.804744 389.556993 -4260997.815768