Co4(OH)4+4

Formula : Co4(OH)4+4

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
303.762 -1000343 (Ref.: 98ply/zha) Plyasunova N. V., Zhang Y., and Muhammed M. (1998) Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions. V. hydrolysis and hydroxo-complexes of Co2+ at 298.15 K. Hydrometallurgy 48(2), 153-169. -1224000 (Ref.: 98ply/zha) Plyasunova N. V., Zhang Y., and Muhammed M. (1998) Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions. V. hydrolysis and hydroxo-complexes of Co2+ at 298.15 K. Hydrometallurgy 48(2), 153-169. -219.685 (Ref.: Internal calculation)
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
Reaction properties

4Co+2 + 4H2O ⇌ Co4(OH)4+4 + 4H+

298.15 K, 1 bar log10K: -29.88 ΔH°r:149720 J·mol-1 (Ref.: 98ply/zha) Plyasunova N. V., Zhang Y., and Muhammed M. (1998) Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions. V. hydrolysis and hydroxo-complexes of Co2+ at 298.15 K. Hydrometallurgy 48(2), 153-169.
T(°C) 0 25 60 100 150 200 250 300
log10K -32.32 -29.88 -27.19 -24.87 -22.69 -20.99 -19.52 -18.05
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
1418.557725 0.212281 -82444.081889 -517.160738 3952728.634616