FeAsO4

Formula : FeAsO4

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
194.766 -13.047 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -744175 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -916105 (Ref.: Internal calculation) -103.345 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -362.88 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
-0.1636 -32.9645 37.3184 -10.2646 -190.0780 -85.0348 -0.1590
Reaction properties

H2AsO4- + Fe+3 ⇌ FeAsO4 + 2H+

298.15 K, 1 bar log10K: -4.43 ΔH°r:42544 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K -5.18 -4.43 -3.73 -3.21 -2.80 -2.48 -2.12 -1.60
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
766.919177 0.128633 -36919.145751 -283.544157 1399287.532493