FeCl+

Formula : FeCl+

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
91.299 1.007 (Ref.: 97sve/sho) Sverjensky, D.A., Shock, E.L., and Helgeson, H.C., 1997 Prediction of the thermodynamic properties of aqueous metal complexes to 1000 C and 5 kb: Geochim. Cosmo. Acta, v. 61, No. 7, pp. 1359-1412. -220835 (Ref.: 04chi) Chivot J., 2004. Thermodynamique des produits de corrosion. Fonctions thermodynamiques de solubilite, diagrammes E-pH des systemes Fe-H2O, Fe-CO2-H2O, Fe-S-H2O, Cr-H2O et Ni-H2O en fonction de la temperature. Document ANDRA, Collection Sciences et Techniques. -235530 (Ref.: 17bbla) Blanc P. (2017) - Thermoddem : Update for the 2017 version. Report BRGM/RP-66811-FR, 20 p. 24.234 (Ref.: Internal calculation) 89.06 (Ref.: 97sve/sho) Sverjensky, D.A., Shock, E.L., and Helgeson, H.C., 1997 Prediction of the thermodynamic properties of aqueous metal complexes to 1000 C and 5 kb: Geochim. Cosmo. Acta, v. 61, No. 7, pp. 1359-1412.
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
8.9822 -10.6136 28.2006 -11.1884 103.3080 4.8606 2.9301
Reaction properties

Cl- + Fe+2 ⇌ FeCl+

298.15 K, 1 bar log10K: -0.16 ΔH°r:21550 J·mol-1 (Ref.: 17bbla) Blanc P. (2017) - Thermoddem : Update for the 2017 version. Report BRGM/RP-66811-FR, 20 p.
T(°C) 0 25 60 100 150 200 250 300
log10K -0.45 -0.16 0.30 0.86 1.57 2.30 3.10 4.05
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
812.113062 0.131821 -46120.837799 -294.239092 2772583.130107