HgCl3-

Formula : HgCl3-

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
306.947 60.865 (Ref.: 97sve/sho) Sverjensky, D.A., Shock, E.L., and Helgeson, H.C., 1997 Prediction of the thermodynamic properties of aqueous metal complexes to 1000 C and 5 kb: Geochim. Cosmo. Acta, v. 61, No. 7, pp. 1359-1412. -314951 (Ref.: 76bae/mes) Baes Jr. C.F., and Mesmer R.E., 1976. The Hydrolysis of Cations. Wiley Interscience, 489 pp. -418769 (Ref.: Internal calculation) 127.654 (Ref.: 97sve/sho) Sverjensky, D.A., Shock, E.L., and Helgeson, H.C., 1997 Prediction of the thermodynamic properties of aqueous metal complexes to 1000 C and 5 kb: Geochim. Cosmo. Acta, v. 61, No. 7, pp. 1359-1412. 441.15 (Ref.: 97sve/sho) Sverjensky, D.A., Shock, E.L., and Helgeson, H.C., 1997 Prediction of the thermodynamic properties of aqueous metal complexes to 1000 C and 5 kb: Geochim. Cosmo. Acta, v. 61, No. 7, pp. 1359-1412.
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
43.9333 74.7275 -5.3426 -14.7164 326.5440 76.1911 4.8852
Reaction properties

3Cl- + Hg+2 ⇌ HgCl3-

298.15 K, 1 bar log10K: 15.06 ΔH°r:-87739 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K 16.65 15.06 13.67 12.81 12.45 12.65 13.33 14.54
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
1750.909169 0.286189 -96316.342448 -635.306939 6568838.909614