KAsO4-2

Formula : KAsO4-2

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
178.017 -9.808 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -955743 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -1042176 (Ref.: Internal calculation) 351.456 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -340.08 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
4.6530 -21.1999 32.2670 -10.7512 -167.4440 -51.5402 8.2483
Reaction properties

H2AsO4- + K+ ⇌ KAsO4-2 + 2H+

298.15 K, 1 bar log10K: -14.00 ΔH°r:119613 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K -16.00 -14.00 -11.91 -10.20 -8.75 -7.82 -7.26 -7.00
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-251.559955 -0.051873 10009.804351 94.532025 -1285682.208187