Litharge

Formula : PbO

Family: 
Oxides
Space group: 
Tetragonal - Ditetragonal Dipyramidal HM symbol (4/m 2/m 2/m) Space Group: P 4/nmm
Dana class: 
4.2.4.1III - 4 Oxide Minerals ; 4.2 Simple Oxides with a cation charge of 2+ (A++ O) ; 4.2.3
High temperature: 
Stable at room temperature.
Geological context: 
As a supergene mineral in the weathered zone of polymetallic ore deposits.

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
223.199 23.910 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950. -189279 (Ref.: Internal calculation) -219409 (Ref.: 98cha) Chase, M.W.J., 1998. NIST-JANAF Thermochemical Tables, Journal of Physical Chemistry Reference Data, Vol. 9, 4th Edition. National Institute of Standards and Technology, Washington DC, 1951 pp. 66.320 (Ref.: 98cha) Chase, M.W.J., 1998. NIST-JANAF Thermochemical Tables, Journal of Physical Chemistry Reference Data, Vol. 9, 4th Edition. National Institute of Standards and Technology, Washington DC, 1951 pp. 45.79 (Ref.: 98cha) Chase, M.W.J., 1998. NIST-JANAF Thermochemical Tables, Journal of Physical Chemistry Reference Data, Vol. 9, 4th Edition. National Institute of Standards and Technology, Washington DC, 1951 pp.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
-200.77 575.90 66.54 (Ref.: 98cha) Chase, M.W.J., 1998. NIST-JANAF Thermochemical Tables, Journal of Physical Chemistry Reference Data, Vol. 9, 4th Edition. National Institute of Standards and Technology, Washington DC, 1951 pp.
Reaction properties

Litharge + 2H+ ⇌ Pb+2 + H2O

298.15 K, 1 bar log10K: 12.63 ΔH°r:-65501 J·mol-1 (Ref.: 98cha) Chase, M.W.J., 1998. NIST-JANAF Thermochemical Tables, Journal of Physical Chemistry Reference Data, Vol. 9, 4th Edition. National Institute of Standards and Technology, Washington DC, 1951 pp.
T(°C) 0 25 60 100 150 200 250 300
log10K 13.68 12.63 11.42 10.31 9.19 8.27 7.46 6.68
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-377.453549 -0.060262 23503.755617 138.164019 -1125144.245368