Melanterite

Formula : FeSO4:7H2O

Family: 
Sulfates
Space group: 
Monoclinic - Prismatic HM symbol (2/m) Space Group: P 21/c
Dana class: 
29.6.10.1VI- 29 Hydrated Acid and Sulfates ; 29.6 Hydrated Acid and Sulfates where A XO4 . x(H2O) ; 29.6.10 Melanterite Group (Heptahydrates, Monoclinic: P21/c)

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
278.018 146.500 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. -2507752 (Ref.: Internal calculation) -3012600 (Ref.: 95par/kho) Parker, V.B., Khodakovsky, I.L. (1995) Thermodynamic properties of aqueous ions (2+ et 3+) of iron and the key compouds of iron. J. Phys. Chem. Ref. Data 24 (5) p. 1699-1745. 409.200 (Ref.: 95par/kho) Parker, V.B., Khodakovsky, I.L. (1995) Thermodynamic properties of aqueous ions (2+ et 3+) of iron and the key compouds of iron. J. Phys. Chem. Ref. Data 24 (5) p. 1699-1745.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
Reaction properties

Melanterite ⇌ Fe+2 + SO4-2 + 7H2O

298.15 K, 1 bar log10K: -2.31 ΔH°r:12450 J·mol-1 (Ref.: 95par/kho) Parker, V.B., Khodakovsky, I.L. (1995) Thermodynamic properties of aqueous ions (2+ et 3+) of iron and the key compouds of iron. J. Phys. Chem. Ref. Data 24 (5) p. 1699-1745.
T(°C) 0 25 60 100 150 200 250 300
log10K -2.47 -2.31 -2.00 -1.52 -0.86 -0.23 0.25 0.41
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-1802.701070 -0.254415 96927.317427 651.163524 -5343746.817726