Formula : Ni5As2
Family:
Dernière mise à jour le 25.01.2021
Ni5As2
THERMODYNAMICS
Individual properties (298.15 K)
|
M g·mol-1 |
V° cm3·mol-1 |
ΔGºf J·mol-1 |
ΔHºf J·mol-1 |
Sº J·mol-1·k-1 |
CP J·mol-1·K-1 |
|---|---|---|---|---|---|
| 443.310 |
-237286  (Ref.: Internal calculation) |
-244600 (Ref.: 05gam/bug) Gamsjager, H., Bugajski, J., Gajda, T., Lemire, R., 2005. Chemical Thermodynamics of Nickel. Elsevier Science. |
196.200 (Ref.: 05gam/bug) Gamsjager, H., Bugajski, J., Gajda, T., Lemire, R., 2005. Chemical Thermodynamics of Nickel. Elsevier Science. |
215.99 (Ref.: 05gam/bug) Gamsjager, H., Bugajski, J., Gajda, T., Lemire, R., 2005. Chemical Thermodynamics of Nickel. Elsevier Science. |
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
|
a J·mol-1·K-1 |
b * 103 J·mol-1·K-2 |
c * 10-5 J·K·mol-1 |
Maier Kelley Ref. |
|---|---|---|---|
| 222.97 | 32.00 | -14.69 |
(Ref.: 05gam/bug) Gamsjager, H., Bugajski, J., Gajda, T., Lemire, R., 2005. Chemical Thermodynamics of Nickel. Elsevier Science. |
Reaction properties
Ni5As2 + O2 + 10H+ ⇌ 5Ni+2 + 2AsH3 + 2H2O
298.15 K, 1 bar
log10K: 49.27
ΔH°r:-476089 J·mol-1 (Ref.: 05gam/bug) Gamsjager, H., Bugajski, J., Gajda, T., Lemire, R., 2005. Chemical Thermodynamics of Nickel. Elsevier Science.
(Ref.: 05gam/bug) Gamsjager, H., Bugajski, J., Gajda, T., Lemire, R., 2005. Chemical Thermodynamics of Nickel. Elsevier Science. | T(°C) | 0 | 25 | 60 | 100 | 150 | 200 | 250 | 300 |
|---|---|---|---|---|---|---|---|---|
| log10K | 56.87 | 49.27 | 40.47 | 32.37 | 24.27 | 17.66 | 12.01 | 6.91 |
