PbAsO4-

Formula : PbAsO4-

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
346.119 -25.108 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -710414 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -813703 (Ref.: Internal calculation) 229.702 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363 -325.79 (Ref.: 07mar/acc) Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52:1343-1363
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
-5.9028 -46.9826 43.3366 -9.6851 -164.7200 -65.8633 3.3070
Reaction properties

H2AsO4- + Pb+2 ⇌ PbAsO4- + 2H+

298.15 K, 1 bar log10K: -11.74 ΔH°r:95026 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K -13.32 -11.74 -10.07 -8.69 -7.47 -6.60 -5.93 -5.33
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
355.333114 0.052767 -20155.817809 -129.483524 462298.908211