Rutile

Formula : TiO2

Family: 
Oxides
Space group: 
Tetragonal - Ditetragonal Dipyramidal H-M Symbol (4/m 2/m 2/m) Space Group: P 4/mnm
Dana class: 
4.4.1.1 (4) Simple Oxides (4.4)with a cation charge of 4+ (A++++ O2) (4.4.1) Rutile group (Tetragonal: P4/mnm)
High temperature: 
High pressure an temperature mineral
Geological context: 
Occurs as accessory mineral in metamorphic, magmatic and hydrothermal rocks.

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
79.869 18.820 (Ref.: 95rob/hem) Robie R.A., and Hemingway B.S., 1995. Thermodynamic properties of minerals and related substances at 298.15 K and 1 Bar (105 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 pp. -888767 (Ref.: Internal calculation) -944000 (Ref.: 89cox/wag) Cox J.D., Wagman D.D., and Medvedev V.A., 1989. CODATA Key Values for Thermodynamics. Hemisphere Publishing Corp., New York, 279 p. 50.620 (Ref.: 89cox/wag) Cox J.D., Wagman D.D., and Medvedev V.A., 1989. CODATA Key Values for Thermodynamics. Hemisphere Publishing Corp., New York, 279 p. 55.08 (Ref.: 89cox/wag) Cox J.D., Wagman D.D., and Medvedev V.A., 1989. CODATA Key Values for Thermodynamics. Hemisphere Publishing Corp., New York, 279 p.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
63.20 11.82 -10.35 (Ref.: 89cox/wag) Cox J.D., Wagman D.D., and Medvedev V.A., 1989. CODATA Key Values for Thermodynamics. Hemisphere Publishing Corp., New York, 279 p.
Reaction properties

Rutile + 2H2O ⇌ Ti(OH)4

298.15 K, 1 bar log10K: -8.86 ΔH°r:300 J·mol-1 (Ref.: 89cox/wag) Cox J.D., Wagman D.D., and Medvedev V.A., 1989. CODATA Key Values for Thermodynamics. Hemisphere Publishing Corp., New York, 279 p.
T(°C) 0 25 60 100 150 200 250 300
log10K -8.74 -8.86 -8.65 -8.04 -6.96 -5.67 -4.30 -2.92
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-467.385954 -0.032546 23089.926352 161.388037 -760896.828743