SeCN^-

Formula : SeCN^-

Dernière mise à jour le 25.01.2021

Individual properties (298.15 K)

M g·mol^-1	V° cm³·mol^-1	ΔGº_f J·mol^-1	ΔHº_f J·mol^-1	Sº J·mol^-1·k^-1	C_P J·mol^-1·K^-1
104.977	49.611 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.	81588 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.	77450 (Ref.: Internal calculation)	194.974 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.	-7.51 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.

HKF coefficients

a₁·10 J·mol^-1·bar^-1	a₂·10^-2 J·mol^-1	a₃ J·K·mol^-1·bar^-1	a₄·10^-4 J·K·mol^-1	c₁ J·mol^-1·K^-1	c₂·10^-4 J·K·mol^-1	ω·10^-5 J·mol^-1
37.1338	58.1250	1.1837	-14.0298	54.7589	-14.9975	3.8618

Reaction properties

CN^- + 0.75HSe^- + 0.25SeO₄^-² + 1.25H⁺ ⇌ SeCN^- + H₂O

298.15 K, 1 bar log₁₀K: 43.89 ΔH°_r:-221410 J·mol^-1

T(°C)	0	25	60	100	150	200	250	300
log₁₀K	47.50	43.89	39.89	36.37	33.08	30.68	28.94	27.83

log₁₀K(T) = A + B·T + C·T^-1 + D·log₁₀(T) + E·T⁻² (T in Kelvin)

A	B	C	D	E
924.205904	0.148087	-39746.951395	-334.096127	3159667.059505