Sudoite(Fe)

Formula : Fe2Al4Si3O10(OH)8

Space group: 
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: C 2/m
Dana class: 
71.4.1.4 (71)Phyllosilicate Sheets of Six-Membered Rings (71.4)interlayered 1:1, 2:1, and octahedra (71.4.1)Chlorite group (Tri-Dioctahedral)
High temperature: 
Around 100C to 600C C according Fe,Mg, Al substitutions.
Geological context: 
Contact, hydrothermal, and regional metamorphism of mafic minerals. A product of low-grade metamorphism of Al, Mg-rich rocks.

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
599.929 204.000 (Ref.: 98hol/pow) Holland T.J.B., and Powell R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, p. 309 343. -7275815 (Ref.: Internal calculation) -7912770 (Ref.: 98hol/pow) Holland T.J.B., and Powell R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, p. 309 343. 457.000 (Ref.: 98hol/pow) Holland T.J.B., and Powell R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, p. 309 343. 604.28 (Ref.: 98hol/pow) Holland T.J.B., and Powell R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, p. 309 343.
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
679.08 358.45 -161.49 (Ref.: 98hol/pow) Holland T.J.B., and Powell R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, p. 309 343.
Reaction properties

Sudoite(Fe) + 16H+ ⇌ 4Al+3 + 2Fe+2 + 3H4SiO4 + 6H2O

298.15 K, 1 bar log10K: 36.17 ΔH°r:-512393 J·mol-1 (Ref.: 98hol/pow) Holland T.J.B., and Powell R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, p. 309 343.
T(°C) 0 25 60 100 150 200 250 300
log10K 44.23 36.17 26.62 17.75 8.77 1.29 -5.36 -11.66
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-3717.513172 -0.559663 229687.375330 1327.839977 -12043570.164616