Svanbergite

Formula : SrAl3(PO4)(SO4)(OH)6

Family: 
Phosphates
Space group: 
Trigonal - Hexagonal ScalenohedralH-M Symbol (3 2/m) Space Group: R 3m

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
461.644 142.270 (Ref.: 04gab/vie) Gaboreau S. and Vieillard Ph. (2004). Prediction of Gibbs free energies of formation of minerals of the alunite supergroup. Geochimica and Cosmochimica Acta, 68, 3307-3316 -5286600 (Ref.: 04gab/vie) Gaboreau S. and Vieillard Ph. (2004). Prediction of Gibbs free energies of formation of minerals of the alunite supergroup. Geochimica and Cosmochimica Acta, 68, 3307-3316 -5791177 (Ref.: Internal calculation) 349.480 (Ref.: 04gab/vie) Gaboreau S. and Vieillard Ph. (2004). Prediction of Gibbs free energies of formation of minerals of the alunite supergroup. Geochimica and Cosmochimica Acta, 68, 3307-3316 94.39 (Ref.: 04gab/vie) Gaboreau S. and Vieillard Ph. (2004). Prediction of Gibbs free energies of formation of minerals of the alunite supergroup. Geochimica and Cosmochimica Acta, 68, 3307-3316
CP(T) = a + b·T + ·c·T-2 (T in Kelvin)
a
J·mol-1·K-1
 b * 103
J·mol-1·K-2
 c * 10-5
J·K·mol-1
 Maier Kelley Ref.
113.63 49.40 -30.20 (Ref.: 04gab/vie) Gaboreau S. and Vieillard Ph. (2004). Prediction of Gibbs free energies of formation of minerals of the alunite supergroup. Geochimica and Cosmochimica Acta, 68, 3307-3316
Reaction properties

Svanbergite + 8H+ ⇌ 3Al+3 + H2PO4- + SO4-2 + Sr+2

298.15 K, 1 bar log10K: 7.75 ΔH°r:-301843 J·mol-1 (Ref.: Internal calculation)
T(°C) 0 25 60 100 150 200 250 300
log10K 12.50 7.75 2.11 -3.21 -8.74 -13.57 -18.16 -22.99
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-3817.194917 -0.598630 218358.666649 1374.636135 -11591926.669320