U+4

Formula : U+4

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
238.029 -53.578 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950. -529904 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950. -591193 (Ref.: Internal calculation) -416.726 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950. 15.95 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
-17.9226 -76.2823 53.9548 -8.4734 168.2780 -12.5261 15.4118
Reaction properties

2H+ + UO2+2 ⇌ U+4 + 0.5O2 + H2O

298.15 K, 1 bar log10K: -33.96 ΔH°r:136009 J·mol-1 (Ref.: 97asho/sas) Shock, E.L., Sassani, D.C., Willis, M., and Sverjensky, D.A., 1997, Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes: Geochim. Cosmo. Acta, v. 61, no. 5, pp. 907-950.
T(°C) 0 25 60 100 150 200 250 300
log10K -36.10 -33.96 -31.41 -28.99 -26.54 -24.58 -22.99 -21.72
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
-241.232279 -0.037334 2650.841284 85.983925 -288716.091386