Zn(HS)3-

Formula : Zn(HS)3-

Dernière mise à jour le 25.01.2021

THERMODYNAMICS

Individual properties (298.15 K)
M
g·mol-1
 V°
cm3·mol-1
 ΔGºf
J·mol-1
 ΔHºf
J·mol-1
 Sº
J·mol-1·k-1
 CP
J·mol-1·K-1
164.612 64.649 (Ref.: 14aki/tag) Akinfiev, N., Tagirov, B., 2014. Zn in hydrothermal systems: thermodynamic description of hydroxide, chloride, and hydrosulfide complexes. Geochemistry International 52, 197-214. -186192 (Ref.: 14aki/tag) Akinfiev, N., Tagirov, B., 2014. Zn in hydrothermal systems: thermodynamic description of hydroxide, chloride, and hydrosulfide complexes. Geochemistry International 52, 197-214. -250258 (Ref.: 14aki/tag) Akinfiev, N., Tagirov, B., 2014. Zn in hydrothermal systems: thermodynamic description of hydroxide, chloride, and hydrosulfide complexes. Geochemistry International 52, 197-214. 184.362 (Ref.: Internal calculation) 293.78 (Ref.: 14aki/tag) Akinfiev, N., Tagirov, B., 2014. Zn in hydrothermal systems: thermodynamic description of hydroxide, chloride, and hydrosulfide complexes. Geochemistry International 52, 197-214.
HKF coefficients
a1·10
J·mol-1·bar-1
 a2·10-2
J·mol-1
 a3
J·K·mol-1·bar-1
 a4·10-4
J·K·mol-1
 c1
J·mol-1·K-1
 c2·10-4
J·K·mol-1
 ω·10-5
J·mol-1
45.7734 79.2052 -7.0739 -14.9017 232.0630 46.3579 3.9464
Reaction properties

3HS- + Zn+2 ⇌ Zn(HS)3-

298.15 K, 1 bar log10K: 13.26 ΔH°r:-47972 J·mol-1 (Ref.: 14aki/tag) Akinfiev, N., Tagirov, B., 2014. Zn in hydrothermal systems: thermodynamic description of hydroxide, chloride, and hydrosulfide complexes. Geochemistry International 52, 197-214.
T(°C) 0 25 60 100 150 200 250 300
log10K 14.17 13.26 12.54 12.18 12.18 12.57 13.33 14.56
log10K(T) = A + B·T + C·T-1 + D·log10(T) + E·T−2 (T in Kelvin)
A B C D E
1888.708686 0.300147 -104040.379752 -683.379854 6666627.764672